By Dr. Glenn T. Seaborg (auth.), Norman M. Edelstein, James D. Navratil, Wallace W. Schulz (eds.)
The papers incorporated during this quantity have been awarded on the symposium on "Americium and Curium Chemistry and expertise" on the foreign Chemical Congress of Pacific Basin Societies in Honolulu, Hawaii, December 16-21, 1984. This symposium venerated 40 years of study on americium and curium. consequently, the papers integrated during this quantity commence with historic views at the discovery of americium and curium and the early characterization in their chemical homes, after which conceal quite a lot of topics, akin to thermodynamic houses, digital constitution, nuclear reactions, analytic chemistry, excessive strain part transitions, and technological facets. hence, this quantity is a evaluate of the chemistry of americium and curium, and gives a point of view at the present learn on those components 40 years after their discovery. The editors want to thank the individuals during this symposium for his or her contributions. it's a excitement to recognize the help of Ms. Barbara Moriguchi in dealing with the executive facets of the symposium and of the construction of this quantity. April 2, 1985 Norman M. Edelstein fabrics and Molecular learn department Lawrence Berkeley Laboratory college of California Berkeley, California 94720, U.S.A. James D. Navratil Rockwell overseas Rocky residences Plant P.O. field 464 Golden, Colorado 80402-0464, U.S.A. Wallace W. Schulz Rockwell Hanford P.O. field 800 Richland, Washington 99352, U.S.A.
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Additional info for Americium and Curium Chemistry and Technology: Papers from a Symposium given at the 1984 International Chemical Congress of Pacific Basin Societies, Honolulu, HI, December 16–27, 1984
R. G. Haire, J. K. Gibson, and U. Benedict for helpful discussions during the preparation of this article. REFERENCES 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. Seaborg, G. T. , Englewood Cliffs, NY (1963). van Spronsen, J. S. The Periodic System of Chemical Elements, Elsevier, Amsterdam (1969). Seaborg, G. , Katz, J. , and Manning, W. M. , New York (1949), pp. 1492-1524. Seaborg, G. T. Chern. Eng. News, ~l, 2190 (1945). , and Ghiorso, A. Inorg. Nucl. Chern. Letters, 2, 733 (1970). , and Ghiorso, A.
Nucl. Chern. Letters, 2, 733 (1970). , and Ghiorso, A. Science, 1~~, 1114 (1968). Kleinschmidt, P. , Ward, J. , and Haire, R. G. Proc. Symp. on High Temp. Materials, Chern II, Vol. 83-7, Z. A. Munir and D. , Pennington, NJ (1983), pp. 23-31. Hubener, S. and Zvara, Radiochemica Acta, lL 89 (1982). , O. L. Paper presented at the International Conference on Nuclear and Radiochemistry, Lindau, FRG, October 1984. To be published in Radiochemica Acta. Benedict, U. J. Less-Common Metals, 1QQ, 153 (1984).
Beta-Diketones have also been used for amerioium and ourium isolation and their following determination. 1-phenyl-)-methyl-4-benzoyl-pyrazolone-5 (PMBP) is the most thoroughly studied example in the works of the soviet authors (66). It extraots a number of elements, inoluding ourium (67) from more aoid media than thenoyltrifluoroaoetone (TTA). The presenoe of salts greatly influenoes amerioium extraotion by this reagent (68). 1 M PMBP solution in benzene from) M lINO) solution (69). nd ourium extraotion by beta-dike tones inorease strongly in the presenoeof organio phase donor aotive additives such as TPB and TOPO (synergistio extraction).