By Faraday M., Crookes W.
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The c y c l i c pathway i s followed u n t i l a l l of the hydrogen atoms are exchanged by deuterium. The key to the mechanistic scheme i s formation and opening of the m e t a l l o c y c l e . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1980. 2. ANDERSEN 43 4i- and 5i-Block Metals reaction of i t with deuterium to yield the perdeutoro-derivative strongly implies that the mechanistic scheme i s essentially correct. The observation that the hydrides, [(Me Si) N]3MH, extrude hydrogen and form the metallocycle is added support for the essential validity of the proposed mechanism.
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