By Mueller J.H.

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M. Gary-Bobo, J. M. Lehn and P. P1umere, Biochem. Biophys. Res. , 116, 981 (1983) . J. F. Koszuk, B. P. Czech, W. Walkowiak, D. A. Babb and R. A. Bartsch, I. Chem. , Chem. , 1504 (1984) . E. Sonveaux, Tetrahedron, 40, 793(1984). M. Dhaenens, L. Lacombe, J. M. Lehn and J. P. Chem. , Chem. , 1097 (1984) . B. P. Bubnis and G. E. ,25, 1107 (1984). S. Inokuma, T. Kohno, K. Inoue, K. Yabusa and T. Kuwamura, 1. Chem. Soc. , Chem. and Ind. , 8, 1585 (1985) . K. Kimura, H. Sakamoto, S. Kitazawa and T. , Chem.

M. Dhaenens, L. Lacombe, J. M. Lehn and J. P. Chem. , Chem. , 1097 (1984) . B. P. Bubnis and G. E. ,25, 1107 (1984). S. Inokuma, T. Kohno, K. Inoue, K. Yabusa and T. Kuwamura, 1. Chem. Soc. , Chem. and Ind. , 8, 1585 (1985) . K. Kimura, H. Sakamoto, S. Kitazawa and T. , Chem. , 669 (1985) . Y. Katayama, K. Nita, M. ueda, H. Nakamura, M. Takagi and K. Acta,173, 193(1985). J. P. Behr, C. J. Burrows, R. Heng and J. M. , 26, 215 (1985) . T. W. Robison and R. A. Bartsch, 1. Soc.. , 990 (1985) . B. P.

2 Biomimetic Complexation Studies. Pedersen [lJ found that macrocyc1ic polyethers, particularly those with the 18-crown-6 cavity, were capable of comp1exing ammonium ions. Cram [6J pointed out that the addition of extra units could give such compounds more shape and additional binding sites. Since then a number of researchers have prepared host molecules which contain a combination of shaped and charged side units in efforts to duplicate the chiral and electrostatic recognition of guest molecules afforded in natural systems by enzymes and proteins.

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