By Bunger J.W., Li N.C. (eds.)
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MARGERUM: Yes, i t does t u r n up i n a number o f i n stances. The example you a r e t a l k i n g about was an EDTA r e a c t i o n w i t h a copper t r i g l y c i n e i n which t h e r e l e a s e d t r i g l y c i n e c a t a l yzed the s u b s t i t u t i o n o f the EDTA. This r e s u l t e d from t h e f a c t t h a t the b i s - t r i g l y c i n e complex i s f a s t e r t o undergo s u b s t i t u t i o n than i s t h e mono complex. The r e l e a s e d t r i g l y c i n e formed a b i s complex and t h e EDTA then attacked t h a t .
Benjamin: New York, 1966. 6. Margerum, D. ; Cayley, G. ; Weatherburn, D. ; Pagenkopf, G. W. "Coordination Chemistry"; Martell, A. ; American Chemical Society: Washington, D. , 1978; Vol. 2, pp 1-220. 7. Stranks, D. ; Swaddle, T. W. J. Am. Chem. Soc. 1971, 93, 2783. 8. Hunt, H. ; Taube, H. J. Am. Chem. Soc. 1958, 80, 2642. 9. Swaddle, T. ; Stranks, D. R. J. Am. Chem. Soc. 1972, 94 8357. 10. Tong, S. ; Swaddle, T. W. Inorg. Chem. 1974, 13, 1538. 11. ; Earl, W. ; Merbach, A. E. Inorg. Chem. 1979, 18, 2754.
1960, 2895. 34. Wilkins, R. G. "The Study of Kinetics and Mechanism of Reactions of Transition Metal Complexes"; Allyn and Bacon: Boston, 1974; pp 108-110, 205-206. 35. Bannister, C. ; Margerum, D. ; Raycheba, J. M. ; Wong, L. F. Faraday Sym. Chem. Soc. 1975, 10, 78. 36. Wong, L. ; Cooper, J. ; Margerum, D. W. J. Am. Chem. Soc. 1976, 98, 7268. 37. Billo, E. J . ; Margerum, D. W. J. Am. Chem. Soc. 1970, 92, 6811. 38. Bannister, C. ; Margerum, D. W. Inorg. Chem. 1981, 20, 3149. 39. Margerum, D. ; Dukes, G.